Acetondikarboksilna kiselina

Acetondikarboksilna kiselina
	3-Oksopentandionska kiselina
Drugi nazivi	1,3-Acetondikarboksilna kiselina; 3-oksoglutarna kiselina; 3-ketoglutarna kiselina; β-ketoglutarna kiselina
Identifikacija
PubChem	68328
ChemSpider	61623
EINECS broj	208-797-9
Jmol-3D slike	Slika 1; Slika 2
SMILES
	C(C(=O)CC(=O)O)C(=O)O O=C(O)CC(=O)CC(=O)O
InChI
	InChI=1S/C5H6O5/c6-3(1-4(7)8)2-5(9)10/h1-2H2,(H,7,8)(H,9,10) ; Kod: OXTNCQMOKLOUAM-UHFFFAOYSA-N InChI=1/C5H6O5/c6-3(1-4(7)8)2-5(9)10/h1-2H2,(H,7,8)(H,9,10); Kod: OXTNCQMOKLOUAM-UHFFFAOYAR
Svojstva
Molekulska formula	C5H6O5
Molarna masa	146,09814 g/mol
Gustina	1,499 g/cm3
Tačka topljenja	133 °C (razlaže se)
Tačka ključanja	408,4 °C (760mm Hg)
Opasnost
Tačka paljenja	214,9 °C
	(šta je ovo?) (verifikuj) ; Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje (25 °C, 100 kPa) materijala
	Infobox references

Acetondikarboksilna kiselina (3-oksoglutarna kiselina je jednostavna karboksilna kiselina, koja se može koristiti kao gradivni blok u organskoj hemiji.

Ona je komercijalno dostupna.^[5] Ova kiselina se može pripremiti putem dekarbonilacije limunska kiselina u dimećoj sumpornoj kiselini:^[6]

Reference[uredi | uredi kod]

↑ 1,3-Acetonedicarboxylic acid at Sigma-Aldrich (safety data sheet)
↑ Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit
↑ Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.
↑ Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit
↑ German patent DE 32245 Farbwerke vormals Meister, Lucius und Brüning in Höchst a. M. (eingereicht 9. November 1884, erteilt 9. July 1885)
↑ Roger Adams, H. M. Chiles, and C. F. Rassweiler (1941), „Acetonedicarboxylic Acid”, Organic Syntheses ; Coll. Vol. 1: 10

[1] 1,3-Acetonedicarboxylic acid at Sigma-Aldrich (safety data sheet)

[2] Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit

[3] Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.

[4] Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit

[5] German patent DE 32245 Farbwerke vormals Meister, Lucius und Brüning in Höchst a. M. (eingereicht 9. November 1884, erteilt 9. July 1885)

[6] Roger Adams, H. M. Chiles, and C. F. Rassweiler (1941), „Acetonedicarboxylic Acid”, Organic Syntheses ; Coll. Vol. 1: 10

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Acetondikarboksilna kiselina

Reference[uredi | uredi kod]

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