Sukcinaldehid

Sukcinaldehid
	Butandial
Drugi nazivi	1,4-Butandion
Identifikacija
CAS registarski broj	638-37-9
PubChem	12524
ChemSpider	12007
Jmol-3D slike	Slika 1
SMILES
	O=CCCC=O
InChI
	InChI=1S/C4H6O2/c5-3-1-2-4-6/h3-4H,1-2H2 ; Kod: PCSMJKASWLYICJ-UHFFFAOYSA-N InChI=InChI=1S/C4H6O2/c5-3-1-2-4-6/h3-4H,1-2H2
Svojstva
Molekulska formula	C4H6O2
Molarna masa	86.09
Agregatno stanje	bezbojna tečnost
Gustina	1,064 g/cm3
Tačka ključanja	58 °C na 9 mm Hg
Rastvorljivost u vodi	sa hidratacijom
	; ; Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje (25 °C, 100 kPa) materijala
	Infobox references

Sukcinaldehid je organsko jedinjenje sa formulom (CH₂CHO)₂. Ovaj tipični dialdehid je veoma reaktivan. Njime se obično rukuje u obliku hidrata ili metanolnog acetala. On je prekurzor tropinona.^[4] On se koristi kao agens za unakrsno povezivanje, ada je srodni dialdehid, glutaraldehid, u široj upotrebi.

Priprema[uredi | uredi kod]

Sukcinaldehidi se fomiraju oksidacijom THF-a hlorom, i naknadnom hidrolizom i hidroformilacijom akroleinskih derivata.

U vodenim rastvorima ovaj molekul se hidratiše i ciklizuje.^[5] On se u metanolu konvertuje u ciklični acetal, 2,5-dimetoksiltetrahidrofuran.^[6]

Reference[uredi | uredi kod]

↑ Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit
↑ Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.
↑ Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit
↑ SAD patent 2710883
↑ Hardy, P. M.; Nicholls, A. C.; Rydon, H. N. "The hydration and polymerisation of succinaldehyde, glutaraldehyde, and adipaldehyde" J. Chem. Soc., Perkin Trans. 2, 1972, 2270-2278. DOI:10.1039/P29720002270
↑ Christian Kohlpaintner, Markus Schulte, Jürgen Falbe, Peter Lappe, Jürgen Weber "Aldehydes, Aliphatic” in Ullmann's Encyclopedia of Industrial Chemistry 2008, Wiley-VCH, Weinheim. DOI: 10.1002/14356007.a01_321.pub2

Spoljašnje veze[uredi | uredi kod]

Portal Hemija

[1] Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit

[2] Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.

[3] Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit

[4] SAD patent 2710883

[5] Hardy, P. M.; Nicholls, A. C.; Rydon, H. N. "The hydration and polymerisation of succinaldehyde, glutaraldehyde, and adipaldehyde" J. Chem. Soc., Perkin Trans. 2, 1972, 2270-2278. DOI:10.1039/P29720002270

[6] Christian Kohlpaintner, Markus Schulte, Jürgen Falbe, Peter Lappe, Jürgen Weber "Aldehydes, Aliphatic” in Ullmann's Encyclopedia of Industrial Chemistry 2008, Wiley-VCH, Weinheim. DOI: 10.1002/14356007.a01_321.pub2

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Sukcinaldehid

Priprema[uredi | uredi kod]

Reference[uredi | uredi kod]

Spoljašnje veze[uredi | uredi kod]

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